Layer-by-Layer Integration of Zirconium Metal-Organic Frameworks onto Activated Carbon Spheres and Fabrics with Model Nerve Agent Detoxification Properties

We report the controlled synthesis of thin films of prototypical zirconium metal-organic frameworks [Zr6O4(OH)(4)(benzene-1,4-dicarboxylate-2-X)(6)] (X = H, UiO-66 and X = NH2, UiO-66-NH2) over the external surface of shaped carbonized substrates (spheres and textile fabrics) using a layer-by-layer method. The resulting composite materials contain metal-organic framework (MOF) crystals homogeneously distributed over the external surface of the porous shaped bodies, which are able to capture an organo-phosphate nerve agent simulant (diisopropylfluorophosphate, DIFP) in competition with moisture (very fast) and hydrolyze the P-F bond (slow). This behavior confers the composite material self-cleaning properties, which are useful for blocking secondary emission problems of classical protective equipment based on activated carbon.